Frequently Asked Questions
What is Avogadro's number and why is it 6.022 × 10<sup>23</sup>?
Avogadro's number (N<sub>A</sub> = 6.02214076 × 10<sup>23</sup> mol<sup>−1</sup>) is defined so that 1 mole of carbon-12 atoms has a mass of exactly 12 grams. The 2019 SI redefinition fixed N<sub>A</sub> to an exact value. It is large because atoms are extremely small: a single carbon atom weighs about 2 × 10<sup>−23</sup> g.
How do I calculate the number of atoms in a sample?
First convert mass to moles: moles = mass / molar mass. Then multiply by Avogadro's number: N = moles × 6.022 × 10<sup>23</sup>. For example, 12 g of carbon = 1 mol, so it contains 6.022 × 10<sup>23</sup> carbon atoms. For compounds, this gives molecules; for ionic compounds, formula units.
What is the mass of a single atom or molecule?
Divide the molar mass by Avogadro's number. A single water molecule: 18.015 g/mol ÷ (6.022 × 10<sup>23</sup>) = 2.99 × 10<sup>−23</sup> g. A single iron atom: 55.845 ÷ (6.022 × 10<sup>23</sup>) = 9.27 × 10<sup>−23</sup> g. These masses are also expressible in atomic mass units (amu or Da), where 1 amu = 1.66054 × 10<sup>−24</sup> g.
What is the difference between atoms, molecules, and formula units?
They are three ways to count the particles in a mole, matching the particle-type selector. Atoms are single elements: one mole of carbon = 6.022 × 10<sup>23</sup> atoms. Molecules are groups of atoms held by covalent bonds: one mole of water = 6.022 × 10<sup>23</sup> H<sub>2</sub>O molecules, but three times as many atoms. Formula units are the smallest whole-number ratio in an ionic compound such as NaCl, which has no discrete molecules: one mole of NaCl = 6.022 × 10<sup>23</sup> formula units, each releasing one Na<sup>+</sup> and one Cl<sup>−</sup> ion. Avogadro's number counts whichever entity you select.
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